Inert Gases: Potentials, Dynamics, and Energy Transfer in Doped CrystalsM.L. Klein Springer Science & Business Media, 06/12/2012 - 268 من الصفحات Research involving the chemical physics of the inert or rare gases continues unabated. This small volume is meant to deal with advances that have occurred in three selected areas over the past decade. It forms a natural outgrowth of earlier reviews and volumes that have dealt almost exclusively with pure rare-gas solids. Originally, a single chapter was envisaged to cover the topic of alloys and impurities in solid rare gases. However, over the past ten years this single chapter spawned many offshoots and eventually the project became too large for a single volume. Thus the present book contains only a small subset of possbile topics involving rare-gas solids intentionally doped with impurities. Chapter 1 gives a brief overview of current research devoted to the rare gases. This is followed by a comprehensive, self-contained chapter dealing with the most recent developments in the area of interatomic inter actions. Chapter 3 is concerned with the lattice dynamics of rare-gas solids doped with an impurity which is either another rare-gas or a small molecule. The final chapter deals with the spectroscopy of vibrating and rotating di atomic impurities in rare-gas solids. The birth of this volume was not without its labour pains. I should like to take this opportunity to thank the various people who have at one time or another been involved throughout its gestation period. Clearly, many important topics are omitted from this volume. |
المحتوى
1 | |
Dynamics of Impure RareGas Crystals | 82 |
Spectroscopy of Vibrational and Rotational Levels of Diatomic | 145 |
d Phonon Sidebands in IR Spectra of the Guest Molecule | 181 |
References | 251 |
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عبارات ومصطلحات مألوفة
absorption acceptor anharmonic Ar-Kr Ar-Xe argon Arora atoms band beam Biesen broadening calculated Chem contribution coupling dephasing diatomic molecules diffusion dipole donor Dubost dynamical electronic Estimated error excitation experimental fluorescence force constant frequency function Green's functions guest molecule Hartree-Fock He-Ar helium host lattice impurity infrared interaction Interatomic potentials intermolecular Kestin Kr-Xe krypton laser lattice vibrations Lett localised mode M.L. Klein Maitland Mannheim Matrix Isolation matrix-isolated Meijdenberg microscopic mole molecular molecular dynamics motion N₂ non-resonant obtained parameters perturbation perturbation theory phonon Phys predicted properties R.A. Aziz Raman rare gases rare-gas crystals refer to rms relaxation rate repulsive wall rms deviations rotational rotational constant scattering solid argon spectra spectroscopy spectrum studied Table term theoretical theory thermal three-body forces tion transition values vibrational energy transfer vibrational relaxation vibrational transition virial coefficients viscosity xenon αβ